Chemical reactivity of [(μ-RSe) (μ-S) {Fe2(CO)6}2(μ4-S)]-: Synthesis and characterization of (μ-RSe) (μ-R'S) {Fe2(CO)6}2(μ4-S) and (μ3-S)2Fe3 (CO)8 [Se(Ph)Fe(CO)2Cp]

Huai Ben Zheng; Shao Bin Miao; Zhong Xia Wang; Zhong Yuan Zhou; Xiang Ge Zhou

doi:10.1016/S0277-5387(00)00317-X

Chemical reactivity of [(μ-RSe) (μ-S) {Fe₂(CO)₆}₂(μ₄-S)]^-: Synthesis and characterization of (μ-RSe) (μ-R'S) {Fe₂(CO)₆}₂(μ₄-S) and (μ₃-S)₂Fe₃ (CO)₈ [Se(Ph)Fe(CO)₂Cp]

Huai Ben Zheng, Shao Bin Miao, Zhong Xia Wang, Zhong Yuan Zhou, Xiang Ge Zhou

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The reaction Of (μ-S₂)Fe₂(CO)₆ with [(μ-RSe) (μ-CO)Fe₂(CO)6]^- gives the anionic complexes [(μ-RSe) (μ-S){Fe₂(CO)₆}₂(μ₄-S)]^- (1). Reactions of 1 with electrophiles such as alkyl halides, acid chlorides and PhN₂BF₄ form neutral complexes (μ-RSe)(μ-R'S) [Fe₂(CO)₆]₂(μ₄-S) (R = Ph, R' = Me 2a; R = Ph, R' = PhCH₂ 2b; R = Et, R' = Me 2c; R = Ph, R' = CH₃C(O) 3a; R = Ph, R' = PhC(O) 3b; R = Et, R' = PhC(O) 3c; R = R' = Ph 4). Treatment of 1 with Cp(CO)₂FeI affords pentanuclear iron complexes (μ-RSe)[μ-Cp(CO)₂FeS][Fe₂(CO)₆]₂(μ₄-S) (R = Ph 5a; R = Et 5b). From the reaction mixture of 1 (R = Ph) and Cp(CO)₂FeI, (μ₃-S)₂Fe₃(CO)₈[Se(Ph)Fe(CO)₂Cp] (6) was also obtained. The structure of complex 6 was determined by single-crystal X-ray analysis. (C) 2000 Elsevier Science Ltd.

Original language	English (US)
Pages (from-to)	713-718
Number of pages	6
Journal	Polyhedron
Volume	19
Issue number	6
DOIs	https://doi.org/10.1016/S0277-5387(00)00317-X
State	Published - Mar 30 2000
Externally published	Yes

Keywords

Iron
Reaction
Selenium
Sulfur
Synthesis

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S0277-5387(00)00317-X

Cite this

@article{5d9e230caad74297a649d497b05793e1,

title = "Chemical reactivity of [(μ-RSe) (μ-S) {Fe2(CO)6}2(μ4-S)]-: Synthesis and characterization of (μ-RSe) (μ-R'S) {Fe2(CO)6}2(μ4-S) and (μ3-S)2Fe3 (CO)8 [Se(Ph)Fe(CO)2Cp]",

abstract = "The reaction Of (μ-S2)Fe2(CO)6 with [(μ-RSe) (μ-CO)Fe2(CO)6]- gives the anionic complexes [(μ-RSe) (μ-S){Fe2(CO)6}2(μ4-S)]- (1). Reactions of 1 with electrophiles such as alkyl halides, acid chlorides and PhN2BF4 form neutral complexes (μ-RSe)(μ-R'S) [Fe2(CO)6]2(μ4-S) (R = Ph, R' = Me 2a; R = Ph, R' = PhCH2 2b; R = Et, R' = Me 2c; R = Ph, R' = CH3C(O) 3a; R = Ph, R' = PhC(O) 3b; R = Et, R' = PhC(O) 3c; R = R' = Ph 4). Treatment of 1 with Cp(CO)2FeI affords pentanuclear iron complexes (μ-RSe)[μ-Cp(CO)2FeS][Fe2(CO)6]2(μ4-S) (R = Ph 5a; R = Et 5b). From the reaction mixture of 1 (R = Ph) and Cp(CO)2FeI, (μ3-S)2Fe3(CO)8[Se(Ph)Fe(CO)2Cp] (6) was also obtained. The structure of complex 6 was determined by single-crystal X-ray analysis. (C) 2000 Elsevier Science Ltd.",

keywords = "Iron, Reaction, Selenium, Sulfur, Synthesis",

author = "Zheng, {Huai Ben} and Miao, {Shao Bin} and Wang, {Zhong Xia} and Zhou, {Zhong Yuan} and Zhou, {Xiang Ge}",

note = "Funding Information: We thank the Chinese Academy of Science and the Educational Ministry of China for financial support.",

year = "2000",

month = mar,

day = "30",

doi = "10.1016/S0277-5387(00)00317-X",

language = "English (US)",

volume = "19",

pages = "713--718",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Limited",

number = "6",

}

TY - JOUR

T1 - Chemical reactivity of [(μ-RSe) (μ-S) {Fe2(CO)6}2(μ4-S)]-

T2 - Synthesis and characterization of (μ-RSe) (μ-R'S) {Fe2(CO)6}2(μ4-S) and (μ3-S)2Fe3 (CO)8 [Se(Ph)Fe(CO)2Cp]

AU - Zheng, Huai Ben

AU - Miao, Shao Bin

AU - Wang, Zhong Xia

AU - Zhou, Zhong Yuan

AU - Zhou, Xiang Ge

N1 - Funding Information: We thank the Chinese Academy of Science and the Educational Ministry of China for financial support.

PY - 2000/3/30

Y1 - 2000/3/30

N2 - The reaction Of (μ-S2)Fe2(CO)6 with [(μ-RSe) (μ-CO)Fe2(CO)6]- gives the anionic complexes [(μ-RSe) (μ-S){Fe2(CO)6}2(μ4-S)]- (1). Reactions of 1 with electrophiles such as alkyl halides, acid chlorides and PhN2BF4 form neutral complexes (μ-RSe)(μ-R'S) [Fe2(CO)6]2(μ4-S) (R = Ph, R' = Me 2a; R = Ph, R' = PhCH2 2b; R = Et, R' = Me 2c; R = Ph, R' = CH3C(O) 3a; R = Ph, R' = PhC(O) 3b; R = Et, R' = PhC(O) 3c; R = R' = Ph 4). Treatment of 1 with Cp(CO)2FeI affords pentanuclear iron complexes (μ-RSe)[μ-Cp(CO)2FeS][Fe2(CO)6]2(μ4-S) (R = Ph 5a; R = Et 5b). From the reaction mixture of 1 (R = Ph) and Cp(CO)2FeI, (μ3-S)2Fe3(CO)8[Se(Ph)Fe(CO)2Cp] (6) was also obtained. The structure of complex 6 was determined by single-crystal X-ray analysis. (C) 2000 Elsevier Science Ltd.

AB - The reaction Of (μ-S2)Fe2(CO)6 with [(μ-RSe) (μ-CO)Fe2(CO)6]- gives the anionic complexes [(μ-RSe) (μ-S){Fe2(CO)6}2(μ4-S)]- (1). Reactions of 1 with electrophiles such as alkyl halides, acid chlorides and PhN2BF4 form neutral complexes (μ-RSe)(μ-R'S) [Fe2(CO)6]2(μ4-S) (R = Ph, R' = Me 2a; R = Ph, R' = PhCH2 2b; R = Et, R' = Me 2c; R = Ph, R' = CH3C(O) 3a; R = Ph, R' = PhC(O) 3b; R = Et, R' = PhC(O) 3c; R = R' = Ph 4). Treatment of 1 with Cp(CO)2FeI affords pentanuclear iron complexes (μ-RSe)[μ-Cp(CO)2FeS][Fe2(CO)6]2(μ4-S) (R = Ph 5a; R = Et 5b). From the reaction mixture of 1 (R = Ph) and Cp(CO)2FeI, (μ3-S)2Fe3(CO)8[Se(Ph)Fe(CO)2Cp] (6) was also obtained. The structure of complex 6 was determined by single-crystal X-ray analysis. (C) 2000 Elsevier Science Ltd.

KW - Iron

KW - Reaction

KW - Selenium

KW - Sulfur

KW - Synthesis

UR - http://www.scopus.com/inward/record.url?scp=0034732008&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0034732008&partnerID=8YFLogxK

U2 - 10.1016/S0277-5387(00)00317-X

DO - 10.1016/S0277-5387(00)00317-X

M3 - Article

AN - SCOPUS:0034732008

SN - 0277-5387

VL - 19

SP - 713

EP - 718

JO - Polyhedron

JF - Polyhedron

IS - 6

ER -