Disulfido iron-manganese carbonyl cluster complexes: Synthesis, structure, bonding and properties of the radical CpFeMn2(CO)7(μ3-S2)2

Richard D. Adams; Erin M. Boswell; Burjor Captain; Shaobin Miao; Chad Beddie; Charles Edwin Webster; Michael B. Hall; Naresh S. Dalal; Narpinder Kaur; David Zipse

doi:10.1016/j.jorganchem.2008.05.029

Disulfido iron-manganese carbonyl cluster complexes: Synthesis, structure, bonding and properties of the radical CpFeMn₂(CO)₇(μ₃-S₂)₂

Richard D. Adams, Erin M. Boswell, Burjor Captain, Shaobin Miao, Chad Beddie, Charles Edwin Webster, Michael B. Hall, Naresh S. Dalal, Narpinder Kaur, David Zipse

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Two new compounds CpFeMn₂(CO)₇(μ₃-S₂)₂ (2) and Cp₃Fe₃Mn(CO)₄(μ₃-S₂)₂(μ₃-S) (3) were obtained by the treatment of [CpFeMn(CO)₅(μ₃-S₂)]₂ (1) with CO at room temperature in the presence of room light.

Original language	English (US)
Pages (from-to)	2732-2738
Number of pages	7
Journal	Journal of Organometallic Chemistry
Volume	693
Issue number	16
DOIs	https://doi.org/10.1016/j.jorganchem.2008.05.029
State	Published - Aug 1 2008
Externally published	Yes

Keywords

Disulfido
Iron
Manganese
Molecular orbitals
Radical

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/j.jorganchem.2008.05.029

Cite this

Adams, R. D., Boswell, E. M., Captain, B., Miao, S., Beddie, C., Webster, C. E., Hall, M. B., Dalal, N. S., Kaur, N., & Zipse, D. (2008). Disulfido iron-manganese carbonyl cluster complexes: Synthesis, structure, bonding and properties of the radical CpFeMn₂(CO)₇(μ₃-S₂)₂. Journal of Organometallic Chemistry, 693(16), 2732-2738. https://doi.org/10.1016/j.jorganchem.2008.05.029

Adams, RD, Boswell, EM, Captain, B, Miao, S, Beddie, C, Webster, CE, Hall, MB, Dalal, NS, Kaur, N & Zipse, D 2008, 'Disulfido iron-manganese carbonyl cluster complexes: Synthesis, structure, bonding and properties of the radical CpFeMn₂(CO)₇(μ₃-S₂)₂', Journal of Organometallic Chemistry, vol. 693, no. 16, pp. 2732-2738. https://doi.org/10.1016/j.jorganchem.2008.05.029

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title = "Disulfido iron-manganese carbonyl cluster complexes: Synthesis, structure, bonding and properties of the radical CpFeMn2(CO)7(μ3-S2)2 ",

abstract = "Two new compounds CpFeMn2(CO)7(μ3-S2)2 (2) and Cp3Fe3Mn(CO)4(μ3-S 2)2(μ3-S) (3) were obtained by the treatment of [CpFeMn(CO)5(μ3-S2)]2 (1) with CO at room temperature in the presence of room light.",

keywords = "Disulfido, Iron, Manganese, Molecular orbitals, Radical",

author = "Adams, {Richard D.} and Boswell, {Erin M.} and Burjor Captain and Shaobin Miao and Chad Beddie and Webster, {Charles Edwin} and Hall, {Michael B.} and Dalal, {Naresh S.} and Narpinder Kaur and David Zipse",

note = "Funding Information: This research was supported by Grants from the National Science Foundation, Grant Nos. CHE-9909017, CHE-0518074 and CHE-0541587, NIRT/DMR 0506946, and the Welch Foundation (A-648). We thank Dr. Matthew Davis for making the magnetic susceptibility measurements. ",

year = "2008",

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doi = "10.1016/j.jorganchem.2008.05.029",

language = "English (US)",

volume = "693",

pages = "2732--2738",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

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TY - JOUR

T1 - Disulfido iron-manganese carbonyl cluster complexes

T2 - Synthesis, structure, bonding and properties of the radical CpFeMn2(CO)7(μ3-S2)2

AU - Adams, Richard D.

AU - Boswell, Erin M.

AU - Captain, Burjor

AU - Miao, Shaobin

AU - Beddie, Chad

AU - Webster, Charles Edwin

AU - Hall, Michael B.

AU - Dalal, Naresh S.

AU - Kaur, Narpinder

AU - Zipse, David

N1 - Funding Information: This research was supported by Grants from the National Science Foundation, Grant Nos. CHE-9909017, CHE-0518074 and CHE-0541587, NIRT/DMR 0506946, and the Welch Foundation (A-648). We thank Dr. Matthew Davis for making the magnetic susceptibility measurements.

PY - 2008/8/1

Y1 - 2008/8/1

N2 - Two new compounds CpFeMn2(CO)7(μ3-S2)2 (2) and Cp3Fe3Mn(CO)4(μ3-S 2)2(μ3-S) (3) were obtained by the treatment of [CpFeMn(CO)5(μ3-S2)]2 (1) with CO at room temperature in the presence of room light.

AB - Two new compounds CpFeMn2(CO)7(μ3-S2)2 (2) and Cp3Fe3Mn(CO)4(μ3-S 2)2(μ3-S) (3) were obtained by the treatment of [CpFeMn(CO)5(μ3-S2)]2 (1) with CO at room temperature in the presence of room light.

KW - Disulfido

KW - Iron

KW - Manganese

KW - Molecular orbitals

KW - Radical

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JF - Journal of Organometallic Chemistry

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