Double-resonance spectroscopy of the high Rydberg states of HCO. V. Rovibronic interactions and l-uncoupling in the (010) manifold

Eric J Zuckerman, Eric E. Mayer, Robert J. Foltynowicz, Jason D. Robinson, Shi Hui Jen, Michael C. Konopka, Todd Sanford, Hartmut G. Hedderich, I. Chia Chen, Edward R. Grant

    Research output: Contribution to journalArticlepeer-review

    9 Scopus citations

    Abstract

    Ionization-detected absorption spectra of autoionization Rydberg states converging to the (010) vibrational level of HCOPLU was reported. Sharp second-photon resonances were observed in transitions from first-photon-prepared transition states. The spectra was compared in order to characterize observed resonances in terms of good angular momentum quantum number, N. The convergence of series to detailed cation-ore rotational quantum numbers, N+ was established by Rydberg analysis.

    Original languageEnglish (US)
    Pages (from-to)5372-5383
    Number of pages12
    JournalJournal of Chemical Physics
    Volume113
    Issue number13
    DOIs
    StatePublished - Oct 1 2000

    ASJC Scopus subject areas

    • General Physics and Astronomy
    • Physical and Theoretical Chemistry

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