Isotope effects in complexed 2,2′-bipyridyl

Armanda Gameiro; R. D. Gillard; M. M. Rashad Bakhsh; Norman H. Rees

doi:10.1039/CC9960002245

Isotope effects in complexed 2,2′-bipyridyl

Armanda Gameiro, R. D. Gillard, M. M. Rashad Bakhsh, Norman H. Rees

Chemistry and Physics

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

Rate constants for the base hydrolysis in water of the tris(2,2′-bipyridyl)iron(II) ion and its perdeuterioisotopomer differ, as do rate and equilibrium constants for the formation in water of 1:1 adducts of hydroxide with the bis(2,2′-bipyridyl)platinum(II) ion and its perdeuterioisotopomer.

Original language	English (US)
Pages (from-to)	2245
Number of pages	1
Journal	Chemical Communications
Issue number	19
DOIs	https://doi.org/10.1039/CC9960002245
State	Published - 1996

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Isotope effects in complexed 2,2′-bipyridyl",

abstract = "Rate constants for the base hydrolysis in water of the tris(2,2′-bipyridyl)iron(II) ion and its perdeuterioisotopomer differ, as do rate and equilibrium constants for the formation in water of 1:1 adducts of hydroxide with the bis(2,2′-bipyridyl)platinum(II) ion and its perdeuterioisotopomer.",

author = "Armanda Gameiro and Gillard, {R. D.} and {Rashad Bakhsh}, {M. M.} and Rees, {Norman H.}",

year = "1996",

doi = "10.1039/CC9960002245",

language = "English (US)",

pages = "2245",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

number = "19",

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T1 - Isotope effects in complexed 2,2′-bipyridyl

AU - Gameiro, Armanda

AU - Gillard, R. D.

AU - Rashad Bakhsh, M. M.

AU - Rees, Norman H.

PY - 1996

Y1 - 1996

N2 - Rate constants for the base hydrolysis in water of the tris(2,2′-bipyridyl)iron(II) ion and its perdeuterioisotopomer differ, as do rate and equilibrium constants for the formation in water of 1:1 adducts of hydroxide with the bis(2,2′-bipyridyl)platinum(II) ion and its perdeuterioisotopomer.

AB - Rate constants for the base hydrolysis in water of the tris(2,2′-bipyridyl)iron(II) ion and its perdeuterioisotopomer differ, as do rate and equilibrium constants for the formation in water of 1:1 adducts of hydroxide with the bis(2,2′-bipyridyl)platinum(II) ion and its perdeuterioisotopomer.

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U2 - 10.1039/CC9960002245

DO - 10.1039/CC9960002245

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JO - Chemical Communications

JF - Chemical Communications

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ER -

Isotope effects in complexed 2,2′-bipyridyl

Abstract

ASJC Scopus subject areas

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