Abstract
N-Acyl tryptophan isopeptides undergo acyl transfer in chemical ligations via 7-, 10-, 11- and 12-membered cyclic transition states to yield natural peptides, representing the first examples of successful isopeptide ligations from N-acyl tryptophan units.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 1594-7 |
| Number of pages | 4 |
| Journal | Organic and Biomolecular Chemistry |
| Volume | 11 |
| Issue number | 10 |
| DOIs | |
| State | Published - Feb 13 2013 |
Keywords
- Acylation
- Molecular Structure
- Peptides
- Stereoisomerism
- Tryptophan
- Journal Article
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