Molecular structure and optical nonlinearity of 1,8-bis(ferrocenyl)-3-t- butyl-oct-3-ene-1,5,7-triyne

Shaobin Miao; Qian Feng Zhang; Wa Hung Leung

doi:10.3184/0308234043431771

Molecular structure and optical nonlinearity of 1,8-bis(ferrocenyl)-3-t- butyl-oct-3-ene-1,5,7-triyne

Shaobin Miao, Qian Feng Zhang, Wa Hung Leung

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

Interaction of 1,8-bis(ferrocenyl)-octatetrayne 1 with one equiv. of t-butyl lithium followed by treatment with water gave 1,8-bis(ferrocenyl)-3-t- butyl-oct-3-ene-1,5,7-triyne 2. The solid-state structure of 2, containing a bent carbon chain between two ferrocenes, has been determined. The nonlinear optical properties of 2 were also investigated.

Original language	English (US)
Pages (from-to)	714-715
Number of pages	2
Journal	Journal of Chemical Research
Issue number	10
DOIs	https://doi.org/10.3184/0308234043431771
State	Published - Oct 2004
Externally published	Yes

Keywords

Crystal structures
Enynes
Ferrocenes
Optical nonlinearity
Polyynes

ASJC Scopus subject areas

General Chemistry

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title = "Molecular structure and optical nonlinearity of 1,8-bis(ferrocenyl)-3-t- butyl-oct-3-ene-1,5,7-triyne",

abstract = "Interaction of 1,8-bis(ferrocenyl)-octatetrayne 1 with one equiv. of t-butyl lithium followed by treatment with water gave 1,8-bis(ferrocenyl)-3-t- butyl-oct-3-ene-1,5,7-triyne 2. The solid-state structure of 2, containing a bent carbon chain between two ferrocenes, has been determined. The nonlinear optical properties of 2 were also investigated.",

keywords = "Crystal structures, Enynes, Ferrocenes, Optical nonlinearity, Polyynes",

author = "Shaobin Miao and Zhang, {Qian Feng} and Leung, {Wa Hung}",

year = "2004",

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language = "English (US)",

pages = "714--715",

journal = "Journal of Chemical Research",

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AU - Miao, Shaobin

AU - Zhang, Qian Feng

AU - Leung, Wa Hung

PY - 2004/10

Y1 - 2004/10

N2 - Interaction of 1,8-bis(ferrocenyl)-octatetrayne 1 with one equiv. of t-butyl lithium followed by treatment with water gave 1,8-bis(ferrocenyl)-3-t- butyl-oct-3-ene-1,5,7-triyne 2. The solid-state structure of 2, containing a bent carbon chain between two ferrocenes, has been determined. The nonlinear optical properties of 2 were also investigated.

AB - Interaction of 1,8-bis(ferrocenyl)-octatetrayne 1 with one equiv. of t-butyl lithium followed by treatment with water gave 1,8-bis(ferrocenyl)-3-t- butyl-oct-3-ene-1,5,7-triyne 2. The solid-state structure of 2, containing a bent carbon chain between two ferrocenes, has been determined. The nonlinear optical properties of 2 were also investigated.

KW - Crystal structures

KW - Enynes

KW - Ferrocenes

KW - Optical nonlinearity

KW - Polyynes

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Molecular structure and optical nonlinearity of 1,8-bis(ferrocenyl)-3-t- butyl-oct-3-ene-1,5,7-triyne

Abstract

Keywords

ASJC Scopus subject areas

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