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Observation of conserved solution-phase secondary structure in gas-phase tryptic peptides

  • Brandon T. Ruotolo
  • , Guido F. Verbeck
  • , Lisa M. Thomson
  • , Kent J. Gillig
  • , David H. Russell

Research output: Contribution to journalArticlepeer-review

Abstract

Results from ion mobility studies of tryptic peptides suggest that, in some cases, the gas-phase structures can be related to the solution-phase structure of the parent protein. The interpretation of ion mobility measurements is supported by results from molecular modeling and H/D exchange experiments on the same peptides. This study clearly illustrates the utility of IM-MS for screening complex mixtures for peptides having intrinsically stable secondary/tertiary structures, and/or posttranslational modification.

Original languageEnglish (US)
Pages (from-to)4214-4215
Number of pages2
JournalJournal of the American Chemical Society
Volume124
Issue number16
DOIs
StatePublished - Apr 24 2002
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • General Chemistry
  • Biochemistry
  • Colloid and Surface Chemistry

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