Oxidative ring opening of 2,5-diarylfurans by Selectfluor®

Stephen J. Blank; Chad E. Stephens

doi:10.1016/j.tetlet.2006.07.071

Oxidative ring opening of 2,5-diarylfurans by Selectfluor^®

Stephen J. Blank, Chad E. Stephens

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

Attempted fluorination of some 2,5-diarylfurans with the N-F reagent Selectfluor^® has led instead to oxidative ring opening of the furan ring to give the cis-enedione, along with traces of the trans isomer, in good isolated yield.

Original language	English (US)
Pages (from-to)	6849-6850
Number of pages	2
Journal	Tetrahedron Letters
Volume	47
Issue number	38
DOIs	https://doi.org/10.1016/j.tetlet.2006.07.071
State	Published - Sep 18 2006
Externally published	Yes

Keywords

Fluorination
Furan
Oxidative ring opening
Selectfluor
cis-Enedione

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

Access to Document

10.1016/j.tetlet.2006.07.071

Cite this

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title = "Oxidative ring opening of 2,5-diarylfurans by Selectfluor{\textregistered}",

abstract = "Attempted fluorination of some 2,5-diarylfurans with the N-F reagent Selectfluor{\textregistered} has led instead to oxidative ring opening of the furan ring to give the cis-enedione, along with traces of the trans isomer, in good isolated yield.",

keywords = "Fluorination, Furan, Oxidative ring opening, Selectfluor, cis-Enedione",

author = "Blank, {Stephen J.} and Stephens, {Chad E.}",

year = "2006",

month = sep,

day = "18",

doi = "10.1016/j.tetlet.2006.07.071",

language = "English (US)",

volume = "47",

pages = "6849--6850",

journal = "Tetrahedron Letters",

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publisher = "Elsevier Limited",

number = "38",

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T1 - Oxidative ring opening of 2,5-diarylfurans by Selectfluor®

AU - Blank, Stephen J.

AU - Stephens, Chad E.

PY - 2006/9/18

Y1 - 2006/9/18

N2 - Attempted fluorination of some 2,5-diarylfurans with the N-F reagent Selectfluor® has led instead to oxidative ring opening of the furan ring to give the cis-enedione, along with traces of the trans isomer, in good isolated yield.

AB - Attempted fluorination of some 2,5-diarylfurans with the N-F reagent Selectfluor® has led instead to oxidative ring opening of the furan ring to give the cis-enedione, along with traces of the trans isomer, in good isolated yield.

KW - Fluorination

KW - Furan

KW - Oxidative ring opening

KW - Selectfluor

KW - cis-Enedione

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DO - 10.1016/j.tetlet.2006.07.071

M3 - Article

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SN - 0040-4039

VL - 47

SP - 6849

EP - 6850

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 38

ER -