Trinuclear metal clusters with three different metal atoms from the insertion of CpCo and Cp*Rh groups into the S-S bonds of [CpFeMn(CO) 5(μ-S2)]2

Richard D. Adams; Erin Boswell; Shaobin Miao; Sanghamitra Sanyal

doi:10.1007/s10876-005-4397-8

Trinuclear metal clusters with three different metal atoms from the insertion of CpCo and Cp*Rh groups into the S-S bonds of [CpFeMn(CO) ₅(μ-S₂)]₂

Richard D. Adams, Erin Boswell, Shaobin Miao, Sanghamitra Sanyal

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Two cobalt containing products CpCoMn₂(CO) ₆(μ₃-S)₂, 2 and Cp₂FeCoMn(CO) ₃(μ₃-S)₂, 3 were obtained from the reaction of [CpFeMn(CO)₅(μ-S₂)]₂, 1 with CpCo(CO)₂ at room temperature. The two rhodium containing products: Cp*RhMn₂(CO)₆(μ₃-S)₂, 4 (11% yield) and CpFeCp*RhMn(CO)₃(μ₃-S) ₂, 5 (9% yield), were obtained from the reaction of 1 with Cp*Rh(CO)₂. Compounds 3 and 5 were characterized structurally by single crystal X-ray diffraction methods. Compounds 3 and 5 both contain triangular clusters of three different types of metal atoms and have triply bridging sulfido ligands on each side of the cluster. A mechanism for their formation from 1 is proposed.

Original language	English (US)
Pages (from-to)	117-126
Number of pages	10
Journal	Journal of Cluster Science
Volume	16
Issue number	2
DOIs	https://doi.org/10.1007/s10876-005-4397-8
State	Published - Jun 2005
Externally published	Yes

Keywords

Disulfido ligand
Iron
Manganese
Mixed metal cluster
Rhodium
cobalt

ASJC Scopus subject areas

Biochemistry
Chemistry(all)
Materials Science(all)
Condensed Matter Physics

Access to Document

10.1007/s10876-005-4397-8

Cite this

@article{3505fbe5b37d497690c1cf08790e9ad4,

title = "Trinuclear metal clusters with three different metal atoms from the insertion of CpCo and Cp*Rh groups into the S-S bonds of [CpFeMn(CO) 5(μ-S2)]2",

abstract = "Two cobalt containing products CpCoMn2(CO) 6(μ3-S)2, 2 and Cp2FeCoMn(CO) 3(μ3-S)2, 3 were obtained from the reaction of [CpFeMn(CO)5(μ-S2)]2, 1 with CpCo(CO)2 at room temperature. The two rhodium containing products: Cp*RhMn2(CO)6(μ3-S)2, 4 (11% yield) and CpFeCp*RhMn(CO)3(μ3-S) 2, 5 (9% yield), were obtained from the reaction of 1 with Cp*Rh(CO)2. Compounds 3 and 5 were characterized structurally by single crystal X-ray diffraction methods. Compounds 3 and 5 both contain triangular clusters of three different types of metal atoms and have triply bridging sulfido ligands on each side of the cluster. A mechanism for their formation from 1 is proposed.",

keywords = "Disulfido ligand, Iron, Manganese, Mixed metal cluster, Rhodium, cobalt",

author = "Adams, {Richard D.} and Erin Boswell and Shaobin Miao and Sanghamitra Sanyal",

note = "Funding Information: This research was supported by a grant from the National Science Foundation, Grant No. CHE-0354892 and the USC NanoCenter.",

year = "2005",

month = jun,

doi = "10.1007/s10876-005-4397-8",

language = "English (US)",

volume = "16",

pages = "117--126",

journal = "Journal of Cluster Science",

issn = "1040-7278",

publisher = "Springer New York",

number = "2",

}

TY - JOUR

T1 - Trinuclear metal clusters with three different metal atoms from the insertion of CpCo and Cp*Rh groups into the S-S bonds of [CpFeMn(CO) 5(μ-S2)]2

AU - Adams, Richard D.

AU - Boswell, Erin

AU - Miao, Shaobin

AU - Sanyal, Sanghamitra

N1 - Funding Information: This research was supported by a grant from the National Science Foundation, Grant No. CHE-0354892 and the USC NanoCenter.

PY - 2005/6

Y1 - 2005/6

N2 - Two cobalt containing products CpCoMn2(CO) 6(μ3-S)2, 2 and Cp2FeCoMn(CO) 3(μ3-S)2, 3 were obtained from the reaction of [CpFeMn(CO)5(μ-S2)]2, 1 with CpCo(CO)2 at room temperature. The two rhodium containing products: Cp*RhMn2(CO)6(μ3-S)2, 4 (11% yield) and CpFeCp*RhMn(CO)3(μ3-S) 2, 5 (9% yield), were obtained from the reaction of 1 with Cp*Rh(CO)2. Compounds 3 and 5 were characterized structurally by single crystal X-ray diffraction methods. Compounds 3 and 5 both contain triangular clusters of three different types of metal atoms and have triply bridging sulfido ligands on each side of the cluster. A mechanism for their formation from 1 is proposed.

AB - Two cobalt containing products CpCoMn2(CO) 6(μ3-S)2, 2 and Cp2FeCoMn(CO) 3(μ3-S)2, 3 were obtained from the reaction of [CpFeMn(CO)5(μ-S2)]2, 1 with CpCo(CO)2 at room temperature. The two rhodium containing products: Cp*RhMn2(CO)6(μ3-S)2, 4 (11% yield) and CpFeCp*RhMn(CO)3(μ3-S) 2, 5 (9% yield), were obtained from the reaction of 1 with Cp*Rh(CO)2. Compounds 3 and 5 were characterized structurally by single crystal X-ray diffraction methods. Compounds 3 and 5 both contain triangular clusters of three different types of metal atoms and have triply bridging sulfido ligands on each side of the cluster. A mechanism for their formation from 1 is proposed.

KW - Disulfido ligand

KW - Iron

KW - Manganese

KW - Mixed metal cluster

KW - Rhodium

KW - cobalt

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U2 - 10.1007/s10876-005-4397-8

DO - 10.1007/s10876-005-4397-8

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