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Metal Carbonyl Derivatives of 1,4-Quinone and 1,4-Hydroquinone

*Corresponding author for this work
  • University of South Carolina
Scholary Output:
Contribution to journal
Article
 Peer-review

Abstract

CpMoMn(CO)5(μ-S2), 1 reacts with 1,4-benzoquinone to yield CpMoMn(CO)5(μ-S2C6H2O2), 2 containing a 1,4-quinonedithiolato ligand formed by replacing two of the hydrogen atoms on one of the C-C double bonds of 1,4-benzoquinone with sulfur atoms from the disulfido ligand in 1. Compound 2 was reduced with hydrogen to yield CpMoMn(CO)5[μ-S2C6H2(OH)2], 3 which contains a 1,4-hydroquinonedithiolato ligand. Compound 3 was reoxidized to 2 with ferrocenium hexafluorophosphate.

Publication Information

Output type

Scholary Output:
Contribution to journal
Article
 Peer-review

Original language

English (US)

Pages from-to (Number of pages)

Pages 5056-5057 (2 pages)

Journal (Volume, Issue Number)

Journal of the American Chemical Society (Volume 126, Issue 16)

Publication milestones

  • Published - 04/28/2004

Publication status

Published - 04/28/2004

ISSN

0002-7863

Publication IDs

  • Scopus: 1942489327
  • PubMed: 15099074
  • ORCID: /0000-0002-1899-773X/work/65876407

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SciVal
FWCI
0.71
SciVal
Author count
2
SciVal
citations
15
SciVal
Paper percentile
65
Scopus
citations
16, opens in new tab
Fractional count
1
Fractional count
0.50
Fractional count
1
Fractional count
0.50
Fractional count
1
Fractional count
1

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Citation count
16
Captures
8