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Trinuclear metal clusters with three different metal atoms from the insertion of CpCo and Cp*Rh groups into the S-S bonds of [CpFeMn(CO) 5(μ-S2)]2

  • Richard D. Adams(corresponding author)
    ,
  • Erin Boswell
    ,
  • Shaobin Miao
    ,
  • Sanghamitra Sanyal
*Corresponding author for this work
  • University of South Carolina
Scholary Output:
Contribution to journal
Article
 Peer-review

Abstract

Two cobalt containing products CpCoMn2(CO) 6(μ3-S)2, 2 and Cp2FeCoMn(CO) 3(μ3-S)2, 3 were obtained from the reaction of [CpFeMn(CO)5(μ-S2)]2, 1 with CpCo(CO)2 at room temperature. The two rhodium containing products: Cp*RhMn2(CO)6(μ3-S)2, 4 (11% yield) and CpFeCp*RhMn(CO)3(μ3-S) 2, 5 (9% yield), were obtained from the reaction of 1 with Cp*Rh(CO)2. Compounds 3 and 5 were characterized structurally by single crystal X-ray diffraction methods. Compounds 3 and 5 both contain triangular clusters of three different types of metal atoms and have triply bridging sulfido ligands on each side of the cluster. A mechanism for their formation from 1 is proposed.

Publication Information

Output type

Scholary Output:
Contribution to journal
Article
 Peer-review

Original language

English (US)

Pages from-to (Number of pages)

Pages 117-126 (10 pages)

Journal (Volume, Issue Number)

Journal of Cluster Science (Volume 16, Issue 2)

Publication milestones

  • Published - 06/2005

Publication status

Published - 06/2005

ISSN

1040-7278

Publication IDs

  • Scopus: 21844472517
  • ORCID: /0000-0002-1899-773X/work/65876395

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citations
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FWCI
0.15
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Author count
4
SciVal
citations
2
SciVal
Paper percentile
40
Fractional count
1
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0.25
Fractional count
3
Fractional count
0.75
Fractional count
1
Fractional count
1

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2
Citation count
3

Funding Details

This research was supported by a grant from the National Science Foundation, Grant No. CHE-0354892 and the USC NanoCenter.
FundersFunding number
USC NanoCenter
-
NSF
CHE-0354892