Metal Carbonyl Derivatives of 1,4-Quinone and 1,4-Hydroquinone

Richard D. Adams; Shaobin Miao

doi:10.1021/ja049170s

Metal Carbonyl Derivatives of 1,4-Quinone and 1,4-Hydroquinone

Richard D. Adams, Shaobin Miao

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

CpMoMn(CO)₅(μ-S₂), 1 reacts with 1,4-benzoquinone to yield CpMoMn(CO)₅(μ-S₂C₆H₂O₂), 2 containing a 1,4-quinonedithiolato ligand formed by replacing two of the hydrogen atoms on one of the C-C double bonds of 1,4-benzoquinone with sulfur atoms from the disulfido ligand in 1. Compound 2 was reduced with hydrogen to yield CpMoMn(CO)₅[^μ-S₂C₆H₂(OH)₂], 3 which contains a 1,4-hydroquinonedithiolato ligand. Compound 3 was reoxidized to 2 with ferrocenium hexafluorophosphate.

Original language	English (US)
Pages (from-to)	5056-5057
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	126
Issue number	16
DOIs	https://doi.org/10.1021/ja049170s
State	Published - Apr 28 2004
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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title = "Metal Carbonyl Derivatives of 1,4-Quinone and 1,4-Hydroquinone",

abstract = "CpMoMn(CO)5(μ-S2), 1 reacts with 1,4-benzoquinone to yield CpMoMn(CO)5(μ-S2C6H2O2), 2 containing a 1,4-quinonedithiolato ligand formed by replacing two of the hydrogen atoms on one of the C-C double bonds of 1,4-benzoquinone with sulfur atoms from the disulfido ligand in 1. Compound 2 was reduced with hydrogen to yield CpMoMn(CO)5[μ-S2C6H2(OH)2], 3 which contains a 1,4-hydroquinonedithiolato ligand. Compound 3 was reoxidized to 2 with ferrocenium hexafluorophosphate.",

author = "Adams, {Richard D.} and Shaobin Miao",

year = "2004",

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doi = "10.1021/ja049170s",

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journal = "Journal of the American Chemical Society",

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T1 - Metal Carbonyl Derivatives of 1,4-Quinone and 1,4-Hydroquinone

AU - Adams, Richard D.

AU - Miao, Shaobin

PY - 2004/4/28

Y1 - 2004/4/28

N2 - CpMoMn(CO)5(μ-S2), 1 reacts with 1,4-benzoquinone to yield CpMoMn(CO)5(μ-S2C6H2O2), 2 containing a 1,4-quinonedithiolato ligand formed by replacing two of the hydrogen atoms on one of the C-C double bonds of 1,4-benzoquinone with sulfur atoms from the disulfido ligand in 1. Compound 2 was reduced with hydrogen to yield CpMoMn(CO)5[μ-S2C6H2(OH)2], 3 which contains a 1,4-hydroquinonedithiolato ligand. Compound 3 was reoxidized to 2 with ferrocenium hexafluorophosphate.

AB - CpMoMn(CO)5(μ-S2), 1 reacts with 1,4-benzoquinone to yield CpMoMn(CO)5(μ-S2C6H2O2), 2 containing a 1,4-quinonedithiolato ligand formed by replacing two of the hydrogen atoms on one of the C-C double bonds of 1,4-benzoquinone with sulfur atoms from the disulfido ligand in 1. Compound 2 was reduced with hydrogen to yield CpMoMn(CO)5[μ-S2C6H2(OH)2], 3 which contains a 1,4-hydroquinonedithiolato ligand. Compound 3 was reoxidized to 2 with ferrocenium hexafluorophosphate.

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Metal Carbonyl Derivatives of 1,4-Quinone and 1,4-Hydroquinone

Abstract

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