Molecular structure and nonlinear optical properties of a tetrasilver(I) phosphonitocavitand

Shaobin Miao; Wen Rui Yao; Dian Shun Guo; Qian Feng Zhang

doi:10.1016/j.molstruc.2003.08.015

Molecular structure and nonlinear optical properties of a tetrasilver(I) phosphonitocavitand

Shaobin Miao, Wen Rui Yao, Dian Shun Guo, Qian Feng Zhang

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

A tetrasilver(I) phosphonitocavitand was synthesized and structurally characterized. The compound crystallizes in the monoclinic space group P2 ₁/n with a = 15.0151(13), b = 39.832(4), c = 15.2479(14) Å β = 95.1000(2)°, V = 9083.3(14) Å³ and Z = 4. The structure contains four coplanar silver atoms bridged by four μ-Cl and one central trapped μ₄-Cl atoms in the inside of the closing bowl-shaped cavitand. Nonlinear optical properties of this metal-cavitand were investigated. Optical liniiting effect with threshold of 0.6 J cm^-2 was observed with the laser pulses of 7 ns at 532 nm.

Original language	English (US)
Pages (from-to)	159-165
Number of pages	7
Journal	Journal of Molecular Structure
Volume	660
Issue number	1-3
DOIs	https://doi.org/10.1016/j.molstruc.2003.08.015
State	Published - Nov 12 2003
Externally published	Yes

Keywords

Crystal structure
Nonlinear optical property
Phosphonitocavitand
Silver(I)

ASJC Scopus subject areas

Analytical Chemistry
Spectroscopy
Organic Chemistry
Inorganic Chemistry

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10.1016/j.molstruc.2003.08.015

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title = "Molecular structure and nonlinear optical properties of a tetrasilver(I) phosphonitocavitand",

abstract = "A tetrasilver(I) phosphonitocavitand was synthesized and structurally characterized. The compound crystallizes in the monoclinic space group P2 1/n with a = 15.0151(13), b = 39.832(4), c = 15.2479(14) {\AA} β = 95.1000(2)°, V = 9083.3(14) {\AA}3 and Z = 4. The structure contains four coplanar silver atoms bridged by four μ-Cl and one central trapped μ4-Cl atoms in the inside of the closing bowl-shaped cavitand. Nonlinear optical properties of this metal-cavitand were investigated. Optical liniiting effect with threshold of 0.6 J cm-2 was observed with the laser pulses of 7 ns at 532 nm.",

keywords = "Crystal structure, Nonlinear optical property, Phosphonitocavitand, Silver(I)",

author = "Shaobin Miao and Yao, {Wen Rui} and Guo, {Dian Shun} and Zhang, {Qian Feng}",

note = "Funding Information: This project was sponsored by the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry of China. Acknowledgement is made to the funds from Anhui Provincial Natural Science Foundation (grant no. 00045105) and the Natural Science Foundation of Shandong Province (grant no. Y2000B05). Copyright: Copyright 2017 Elsevier B.V., All rights reserved.",

year = "2003",

month = nov,

day = "12",

doi = "10.1016/j.molstruc.2003.08.015",

language = "English (US)",

volume = "660",

pages = "159--165",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

publisher = "Elsevier",

number = "1-3",

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TY - JOUR

T1 - Molecular structure and nonlinear optical properties of a tetrasilver(I) phosphonitocavitand

AU - Miao, Shaobin

AU - Yao, Wen Rui

AU - Guo, Dian Shun

AU - Zhang, Qian Feng

N1 - Funding Information: This project was sponsored by the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry of China. Acknowledgement is made to the funds from Anhui Provincial Natural Science Foundation (grant no. 00045105) and the Natural Science Foundation of Shandong Province (grant no. Y2000B05). Copyright: Copyright 2017 Elsevier B.V., All rights reserved.

PY - 2003/11/12

Y1 - 2003/11/12

N2 - A tetrasilver(I) phosphonitocavitand was synthesized and structurally characterized. The compound crystallizes in the monoclinic space group P2 1/n with a = 15.0151(13), b = 39.832(4), c = 15.2479(14) Å β = 95.1000(2)°, V = 9083.3(14) Å3 and Z = 4. The structure contains four coplanar silver atoms bridged by four μ-Cl and one central trapped μ4-Cl atoms in the inside of the closing bowl-shaped cavitand. Nonlinear optical properties of this metal-cavitand were investigated. Optical liniiting effect with threshold of 0.6 J cm-2 was observed with the laser pulses of 7 ns at 532 nm.

AB - A tetrasilver(I) phosphonitocavitand was synthesized and structurally characterized. The compound crystallizes in the monoclinic space group P2 1/n with a = 15.0151(13), b = 39.832(4), c = 15.2479(14) Å β = 95.1000(2)°, V = 9083.3(14) Å3 and Z = 4. The structure contains four coplanar silver atoms bridged by four μ-Cl and one central trapped μ4-Cl atoms in the inside of the closing bowl-shaped cavitand. Nonlinear optical properties of this metal-cavitand were investigated. Optical liniiting effect with threshold of 0.6 J cm-2 was observed with the laser pulses of 7 ns at 532 nm.

KW - Crystal structure

KW - Nonlinear optical property

KW - Phosphonitocavitand

KW - Silver(I)

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U2 - 10.1016/j.molstruc.2003.08.015

DO - 10.1016/j.molstruc.2003.08.015

M3 - Article

AN - SCOPUS:0142214676

SN - 0022-2860

VL - 660

SP - 159

EP - 165

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

IS - 1-3

ER -

Molecular structure and nonlinear optical properties of a tetrasilver(I) phosphonitocavitand

Abstract

Keywords

ASJC Scopus subject areas

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